By H. Fischer (auth.), H. Fischer (eds.)
Free radicals, that are key intermediates in lots of thermal, photochemical and radiation tactics, are very important for a formal knowing of primary average approaches and the profitable improvement of natural syntheses. After approximately one decade quantity II/18 serves as a complement and extension to quantity II/13 and covers fee constants and different kinetic info of loose radical reactions in beverages. moreover II/18 comprises new chapters on reactions of radicals in excited states and of carbenes, nitrenes and analogues. chosen species in aqueous recommendations for which different compilations can be found have been intentionally passed over as ahead of, and for a similar cause electron move equilibria of natural radicals weren't covered.
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Extra info for Carbon-Centered Radicals I
10gM-‘s-l A,,, = 330 nm s=4*104M-‘cm- 64) Errors kc30%, Land&-BCmstein New Series 11/18a A,,, not larger than f 5 nm, E< 30%. 1 Self reactions Radical‘s gross formula Reaction Radical generation Method [Ref. p. / add. ref. lOsM-‘s-l OH I Phot. of corresp. ketone KAS methanol ethanol n-propanol Phot. KAS Phot. 168M) 240 ... 18(l). 52(3)- IO* M - 1s- 1 (continued) 64) Errors k-c30%, A,,,,, not larger than f 5 nm, E< 30%. 02 M (C6H,),CHOH. 66) See Fig. 1, p. 16. “) Product analysis indicates 100% combination, Ref.
Ref. 10* M-Is-’ [Ct&DsOl HO D D . 103M-‘s-l CC,bNl C 2 ON-CH, e Phot. 0(1)~109M-‘s-1 products Phot. 0. 52) [83Gill] is an editorially corrected version of [82Gill]. 1 Self reactions Radical’s gross formula Reaction Radical generation Method OCH, [Ref. p. / add. ref. 15(7). 5) sl) 86Buxl CGHIONI 2 = H,C Phot. of 2,2-dimer KESR 2 . D- dimer MTHF OC(O)CH, 193 173 ... 0. Landolt-E4mstcin New Series 11/18a Ref. p. / add. ref. Rate data T CKI CGHIONW I 2 CH, = -I radical pair A- dimer -2 ‘COOCH, Phot.
18(13). lo5 Me2s-‘. 59) Data derived using ~=900OM-~ cm-’ at I=315 nm. Land&-B8mstein New Series II/l& [Ref. p. / add. ref. 4(8)*10gM-‘s-l 83Cial products CH,O Phot. of dimethoxydibenzyl ketone cyclohexane KAS. mal= 321 nm E32, = 1900(400)M-1cm-1 CWWI 2 CH,O-@H, products - Phot. 6*10*M-‘s-l 84Man 1 CGH, ,I FCH3 - products CH3 Phot. 65 - 104s-‘. 1 Self reactions Ref. p. / add. ref. 6(4)*108M-‘s-r 84Soll products H OH Pulse rad. of tryptophan in HzO, NzO satd. 5 ... 5) CH,CH-COO- IIIH + - products 3 Pulse rad.